Synthesis Of Functionalized Cyanopyrazoles Via Magnesium Bases

Allan Dishington,J Lyman Feron,Kathryn Gill,Mark A Graham,Ian Hollingsworth,Jennifer H Pink,Andrew Roberts,Iain Simpson,Matthew Tatton

ORGANIC LETTERS（2014）

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摘要

4-Alkyl- and 4-H-pyrazoles were sequentially metalated using TMPMgCl center dot LiCl, and their reaction with electrophiles afforded 3-aryl-4-alkyl-5-cyanopyrazoles.

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关键词

functionalized cyanopyrazoles,magnesium,synthesis

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