Multifunctional Phenomena in Rare-Earth Intermetallic Compounds With a Laves Phase Structure: Giant Magnetostriction and Magnetocaloric Effect

We report on the magnetic and thermal properties [magnetization, specific heat, thermal expansion, magnetostriction, and magnetocaloric effect (MCE)] for the three multicomponent systems TbxDyyGdzCo2, TbxDyyHoz(Co, Fe)2, and TbxDyyErz(Co, Fe)2 (x + y + z = 1). We show that for TbxDyyRzCo2, the Curie temperatures, TC (which ranged from 130 to 300 K), and order of the phase transition (first or second order) could be controlled by composition. The highest MCE values (the adiabatic temperature change ΔTad = 2.2-2.3 K at μ0ΔH = 1.8 T) were observed for the compounds exhibiting the transitions of the first order. Giant volume magnetostriction of 1500-2000 and 500-600 ppm is demonstrated at a field of μ0H = 10 and 1.2 T, respectively. Structural and magnetic entropy contributions to the total isothermal entropy change are estimated for TbxDyyRzCo2. Regular recurrence and/or change of the physical properties across the varied composition of the compounds allows us to find the materials with desired magnetic characteristics, such as TC, MCE, and magnetostriction, to use them in practice.