Divergent regioselectivity in the synthesis of trisubstituted allylic alcohols by nickel- and ruthenium-catalyzed alkyne hydrohydroxymethylation with formaldehyde.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION（2011）
摘要
The reaction of usymmetrically substituted alkynes with paraformaldehyde proceeds with complete stereoselectivity.
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关键词
hydrohydroxymethylation,nickel,paraformaldehyde,reductive coupling,ruthenium
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