Preparation of Polyfunctional Zinc Organometallics Using an Fe- or Co-catalyzed Cl/Zn-exchange.
Organic letters(2011)
摘要
A new Fe- or Co-catalyzed Cl/Zn-exchange reaction allows the direct transformation of aryl, heteroaryl, and also alkyl chlorides into the corresponding zinc reagents. The method tolerates functional groups such as a nitrile or an ester. Remarkably, secondary and tertiary alkyl chlorides are suitable substrates for the Cl/Zn exchange.
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