Chiral Textures Inside 2D Achiral Domains
Journal of the American Chemical Society(2011)
摘要
Chiral interfaces are of capital importance for biorecognition processes and nanotechnology. In this work, a mixed Langmuir monolayer was built using a surface-active dye and a phospholipid. The monolayer displayed optical activity. The driving force for the formation of the supramolecular chirality is the self-assembly of the polar head-groups of the dye. The existence of supramolecular chirality inside nonchirally-shaped domains is shown.
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