Synthesis Of (-)-Swainsonine And (-)-8-Epi-Swainsonine By The Addition Of Allenylmetals To Chiral Alpha,Beta-Alkoxy Sulfinylimines

Julien Louvel,Fabrice Chemla,Emmanuel Demont,Franck Ferreira,Alejandro Perez-Luna

ORGANIC LETTERS（2011）

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摘要

The asymmetric synthesis of (-)-swainsonine and (-)-8-epi-swainsonine is reported through the addition of either the allenylzinc or the allenyl lithio cyanocuprate reagents derived from [3-(methoxymethoxy)prop-1-ynyl]trimethylsilane to enantiopure alpha,beta-dialkoxy N-tert-butanesulfinylimines derived from D-erythronolactone.

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