Convergent formal synthesis of (±)-roseophilin.

Chuanjun Song,Hui Liu,Meiling Hong,Yuanyuan Liu,Feifei Jia,Li Sun,Zhenliang Pan,Junbiao Chang

JOURNAL OF ORGANIC CHEMISTRY（2012）

引用 34|浏览5

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摘要

A facile convergent synthesis of the tricyclic core 2 of roseophilin is described, which represents the shortest route so far for the formal synthesis of roseophilin. The key step was a tandem pyrrole acylation-Nazarov cyclization reaction to form the cyclopenta[b]pyrrole moiety 4.

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