A stereodynamic and redox-switchable encapsulation-complex containing a copper ion held by a tris-quinolinyl basket.

Sandra Stojanović,Daniel A Turner,Andrew I Share,Amar H Flood,Christopher M Hadad,Jovica D Badjić

CHEMICAL COMMUNICATIONS（2012）

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摘要

We investigated the coordination of Cu(I)/Cu(II) ions to chiral basket (S-3)-1. The results of both experimental and computational studies suggest the formation of a copper redox-switchable system capable of entrapping CH3CN.

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