Carbene spacers in bis-porphyrinic scaffolds.
CHEMICAL COMMUNICATIONS(2012)
摘要
The preparation of two meso-imidazolylporphyrins was achieved in good yield by Ullmann coupling between a meso-bromotriarylporphyrin and imidazoles. Subsequent alkylation afforded the corresponding imidazolium functionalized porphyrins as direct precursors of the carbene. The complexation of these azolium salts with palladium led to trans-anti bis-porphyrin carbenic complexes.
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关键词
bis-porphyrinic
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