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Gargantulide A, a Complex 52-Membered Macrolactone Showing Antibacterial Activity from Streptomyces sp.

Jung-Rae Rho,Gurusamy Subramaniam,Hyukjae Choi,Eun-Hee Kim,Sok Peng Ng,K Yoganathan,Siewbee Ng,Antony D Buss,Mark S Butler,William H Gerwick

Organic Letters（2015）

Cited 12|Views21
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Abstract
Gargantulide A (1), an extremely complex 52-membered macrolactone, was isolated from Streptomyces sp. A42983 and displayed moderate activity against MRSA. The planar structure of 1 was determined using 2D NMR, and its stereochemistry was partially established on the basis of NOESY correlations, J-based configuration analysis, and Kishi’s universal NMR database.
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Key words
small molecule inhibitors,structure elucidation
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