1D chain coordination assembly of [Mn 4 (hmp) 6 (NO 3 ) 2 ] 2+ single-molecule magnets linked by the photochromic [FeNO(CN) 5 ] 2− precursor

L A Kushch,V D Sasnovskaya,E B Yagubskii,S S Khasanov,Sergey V Simonov,R P Shibaeva,A V Korolev,D V Starichenko,A O Anokhin,Valentin Yu Irkhin,Yuri N Shvachko

Inorganica Chimica Acta（2011）

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摘要

The first heterometallic chain cluster {[Mn4(hmp)6(NO3)2FeNO(CN)5·4CH3CN}n (1) based on the [Mn4(hmp)6] SMM has been synthesized. 1 has one-dimensional chain structure: the [Mn4(hmp)6] units are linked via CN-groups of nitroprusside anions. Its magnetic and relaxation properties and low temperature IR spectra under light irradiation have been investigated. The ferromagnetic exchange constants have been calculated.

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关键词

Single-molecule magnets (SMMs),Single-chain magnets (SCMs),One-dimensional chain,Photochromic FeNO(CN)5 anion,Jahn–Teller elongation,Magnetic susceptibility

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