Bulking up: Hexanuclear oximato Fe(III) complexes surrounded by sterically demanding co-ligands

Edel Houton,Sean T. Meally,Sergio Sanz,Euan K. Brechin,Leigh F. Jones

Inorganica Chimica Acta（2014）

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摘要

Bulking up: sterically demanding oxime and carboxylate ligands combine to aid the self-assembly of hexanuclear [Fe6] cages. Magnetic susceptibility measurements reveal dominant antiferromagnetic exchange between the Fe(III) centres.

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关键词

Coordination chemistry,Ferric cages,Molecular magnetism

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