Two new metal–organic framework structures derived from terephthalate and linear trimetallic zinc building units

Nathalie Saffon-Merceron,Marie-Claire Barthélémy,Christophe Laurent,Isabelle Fabing,Pascal Hoffmann,Alain Vigroux

Inorganica Chimica Acta（2015）

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摘要

The structures of MOF 1 and 2 comprise stacked 36 tessellated 2D zinc-terephthalate layers. The layers are linked into 3D frameworks by bridging formate monoanions (1) or by neutral Zn(HCO2)2(DEF)4 units (2).

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关键词

Metal–organic framework,Terephthalate,Zinc(II) trimer,Formate ligand,Supercritical-CO2 activation

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