Effect of Flow Depth and Velocity on Nitrate Loss Rates in Natural Channels1

Carleton, James N. and Yusuf M. Mohamoud, 2012. Effect of Flow Depth and Velocity on Nitrate Loss Rates in Natural Channels. Journal of the American Water Resources Association (JAWRA) 1-12. DOI: 10.1111/jawr.12007 Abstract: Loss rates of nitrate from streams and rivers are governed by movement of the ion from water column to anoxic bed sediments. Quantitative representations of nitrate in streams and rivers have often treated such losses as governed by first-order mechanisms that are invariant with respect to potential modulating factors other than temperature. Results of studies in recent years, however, suggest that rates of water column-sediment mass transfer are influenced by stream geometry and associated hydraulics. We develop expressions for the instream nitrate loss rate coefficient, k, as a function of water velocity and depth, using hydraulic geometry to empirically relate velocity to depth for two cases: (1) variability in mean conditions among reaches; and (2) temporal variability in conditions at a single reach, under changing flow. The result is expressions for k as functions of water column depth. Measured stream k values reported in the literature are shown to be well represented by expressions developed for the first case, and the potential for application to probabilistic analysis is briefly examined. We explore the latter case using the Hydrologic Simulation Program FORTRAN (HSPF) model, modified to incorporate the dependence of k on instantaneous stream depth. In example simulations of two nitrate-exporting watersheds, the incorporation of depth-dependence of k produces improvement in the model's ability to match observed stream nitrate concentrations.