Infrared spectroscopy at high temperature : N 2 - and O 2 -broadening coefficients in the ν4 band of CH 4

Journal of Molecular Spectroscopy(2015)

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摘要
•First determination of the N2- and O2-broadening of lines in the ν4 band of methane at high temperature were realized.•Set-up and development of a high temperature absorption cell for infrared spectroscopy was realized.•N2- and O2-broadening temperature dependence of lines in the ν4 band of methane were measured accuracy.•The line parameters were measured by high resolution diode-laser spectroscopy.•The line parameters were deduced from Voigt, Rautian-Sobel’man and Galatry fits.
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关键词
High-temperature,Infrared spectroscopy,Collisional-broadening,CH4,Diode-laser
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