The silane isotopomers 29SiH4 and 30SiH4 constants of the ν2/ν4 dyad
CANADIAN JOURNAL OF PHYSICS(2011)
摘要
The IR spectrum of two silane isotopomers containing 29Si and 30Si was investigated with CO2 laser side bands in the range between 877 and 954 cm−1 at a resolution of 2 × 10−5 cm−1. An analysis of the ν2 and (or) ν4 dyad has been performed, including data obtained by Henry and Valentin from a Fourier transform spectrum and sub-Doppler lines observed by Borde (Rev. Cethedec-Ondes NS, 83(1), 1 (1983)) and Skrzypczak et al. (J. Mol. Spectrosc. 138, 311 (1989)). From the fit 41 vibration–rotation constants, tΩ(K,nΓ) of the ν2/ν4 Hamiltonian have been determined.
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