Determination of thermodynamic stability of lanthanum chloride hydrates (LaCl 3 ⋅ x H 2 O) by dynamic transpiration method

Journal of Alloys and Compounds(2014)

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摘要
•Mechanism of thermal decomposition of LaCl3⋅7H2O is reinvestigated.•Vapor pressure of H2O over LaCl3⋅7H2O and the decomposed products were measured.•Thermodynamic stability of LaCl3⋅7H2O and its decomposed products were determined.
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关键词
Vapor pressure measurement,Transpiration technique,Free energy of formation LaCl3⋅xH2O
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