Concise total synthesis of (±)-pisiferin

Tetrahedron(2015)

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摘要
A concise total synthesis of (±)-pisiferin has been accomplished from commercially available compounds α-cyclocitral (9) and 4-bromo-2-isopropylphenol (10) via Suzuki coupling and F–C alkylation as key reaction in five steps with an overall yield of 22%. The feature of this concise synthesis is a convergent strategy coupled by Suzuki reaction. This work not only provides a strategy to approach the total synthesis of pisiferin itself but also serves as an additional correlation origin to which many related icetaxane-type diterpenes can be referred.
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关键词
Icetaxane-type diterpenes,Total synthesis,Pisiferin,Suzuki coupling,F–C alkylation
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