Studies towards the synthesis of secoiridoids

Tetrahedron(2015)

引用 6|浏览17
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摘要
A new approach to secoiridoids, based on the synthesis of the key functionalized intermediates 4 and 5, is presented. These compounds were tested in formal [3+3] cycloadditions. Acyl-chloride 15 was transformed into enol α,β-unsaturated ester 16, which was involved in a N-heterocyclic carbene rearrangement to give an advanced precursor 17 in the total synthesis of secoiridoids.
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关键词
Secoiridoids,Gentiopicroside,Organocatalysis,[3+3] Cycloadditions,N-heterocyclic-carbenes
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