Sulfur Vulcanization of Simple Model Olefins, Part V: Double Bond Isomerization During Accelerated Sulfur Vulcanization As Studied by Model Olefins
Rubber chemistry and technology(1997)
Abstract
The sulfur vulcanization of unsaturated rubber has been studied with the use of various olefins as simple, low-molecular models. By treatment of these olefins with a mixture of zinc oxide, sulfur, and tetramethylthiuram disulfide (TMTD) at 140 degrees C, a mixture of dialkenyl sulfides is obtained mimicking crosslinked rubber. Isomerization of the double bond may take place during this reaction, depending on the olefin used. The position of the double bond is on the one hand determined by crosslink formation mechanisms, and on the other hand by isomerization, which takes place at higher temperatures. The position of the equilibrium between isomeric alkenyl sulfides is determined by the increased stability of the sulfide which in itself results from an increased degree of alkyl substitution at the unsaturation. Due to the isomerization reaction, at higher temperatures no mechanism for crosslink formation can be discerned. At room temperature, however, a radical mechanism appears to be predominant during the vulcanization process.
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