Palladium nanoparticles supported on Smopex (R) metal scavengers as catalyst for carbonylative Sonogashira reactions: Synthesis of alpha,beta-alkynyl ketones

Laura Antonella Aronica,Anna Maria Caporusso,Giulia Tuci,Claudio Evangelisti,Maela Manzoli,M A Botavina,Gianmario Martra

Applied Catalysis A: General（2014）

引用 19|浏览17

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摘要

•Palladium nanoparticles (Pd NP) prepared by means of metal vapour synthesis technique.•Deposition of Pd NP on Smopex® metal scavengers.•Pd/Smopex®-234 catalyses selectively carbonylative Sonogashira reactions.•Preliminary tests indicate a heterogeneous behaviour.

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关键词

Palladium nanoparticles,Heterogeneous catalysis,Sonogashira cross-coupling carbonylation,Metal vapour synthesis

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