ChemInform Abstract: γ‐Selective Directed Catalytic Asymmetric Hydroboration of 1,1‐Disubstituted Alkenes.

Sean M Smith,Gia L Hoang,Rhitankar Pal, Mohammad O Bani Khaled, Liberty S W Pelter,Xiao Cheng Zeng,James M Takacs

Cheminform（2013）

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摘要

In contrast to tri- and other disubstitution patterns, catalytic asymmetric hydroboration of title compounds (I) and (IX) affords γ-borylated products such as (III) and proceeds in the opposite sense of asymmetric induction.

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