ChemInform Abstract: Oscillatory Template Exchange in Polyoxometallate Capsules: A Ligand‐Triggered, Redox‐Powered, Chemically Damped Oscillation.

Haralampos N Miras,Marjorie Sorus,Jonathan Hawkett,D Sells,Eric J L Mcinnes,Leroy Cronin

Cheminform（2012）

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摘要

An oscillatory template exchange between phosphate and vanadate anions in an aqueous mixture of (NH 4 ) 6 P 2 Mo 18 O 62 , triethanolamine, and NH 4 VO 3 (80—90 °C) is monitored by ESI‐MS, EPR, and UV/VIS spectroscopy.

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polyoxometallate capsules,cheminform abstract,oscillatory template exchange,ligand-triggered,redox-powered

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