Dinuclear manganese, iron, chromium, and cobalt complexes derived from aroylhydrazone ligands: Synthetic strategies, crystal structures, and magnetic properties

Comptes Rendus Chimie(2015)

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摘要
•Synthetic strategies employed to obtain new and magnetically interesting dinuclear molecules based on iron, manganese, chromium, and cobalt metal ions.•Compared crystal structures of 15 dinuclear complexes.•Very strong ferromagnetic interactions in Mn3+ dinuclear compounds.•Magnetostructural correlations discussed.•Compared data from theoretical calculations.
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关键词
Coordination chemistry,Transition metals,Ligand design,Crystal structure,Magnetic properties
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