Reactive perfluoropolyoxyalkylene oligomers. II. Isothermal equilibrium on silica gel: Macromolecular aggregation
Journal of Fluorine Chemistry(2015)
摘要
Apparent irreversibility of the adsorption of bifunctional oligomers and progressive loss of efficiency of the silica gel: over-aggregation inside the pores (“size confinement effect”) and clusters formation at high concentration level (“size exclusion effect”).
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关键词
Perfluoropolyethers,Silica gel,Hydrogen bonding,Aggregation,Size exclusion,Size confinement
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