The Influence of Electronic Perturbations on the Sulfur-Fluorine Gauche Effect

C Thiehoff,Lukas Schifferer,Constantin G Daniliuc,Nico Santschi,Ryan Gilmour

Journal of Fluorine Chemistry（2016）

引用 17|浏览3

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摘要

•Solution phase conformer populations determined using NMR.•A gauche arrangement predominates over the anti.•The gauche conformer molar fractions notably depend on the para-phenyl substituent.•Average gauche populations increase in the order sulfide, sulfone and sulfoxide.

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关键词

Conformation analysis,Hyperconjugation,NMR spectroscopy,Physical organic chemistry,Sulfur–Fluorine Gauche Effect

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