One-pot Synthesis of Copper-Doped Graphitic Carbon Nitride Nanosheet by Heating Cu–melamine Supramolecular Network and Its Enhanced Visible-Light-driven Photocatalysis

Here we report a novel synthetic pathway for preparation of Cu-doped g-C3N4 (Cu-g-C3N4) with nanosheet morphology by using a two dimensional Cu–melamine supramolecular network as both sacrificial template and precursor. The specific surface area of Cu-g-C3N4 is 40.86m2g−1, which is more than 7 times larger than that of pure g-C3N4. Cu-g-C3N4 showed strong optical absorption in the visible-light region and expanded the absorption to the near-infrared region. The uniform nanosheet morphology, higher surface area and strong visible-light absorption have enabled Cu-g-C3N4 exhibiting enhanced visible light photocatalytic activity for the photo-degradation of methylene blue (MB). The results indicate that metal–melamine supramolecular network can be promising precursors for the one step preparation of efficient metal-doped g-C3N4 photocatalysts.