Thermodynamic properties of Ca1 − x Er x F2 + x and Ca1 − x Yb x F2 + x heterovalent solid solutions

N V Moiseev,P A Popov,P P Fedorov,E A Garibin,V M Reiterov

Inorganic Materials（2013）

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摘要

The heat capacity of single crystals of the Ca1 − x Er x F2 + x (x = 0.05, 0.10) and Ca0.95Yb0.05F2.05 fluorite solid solutions was determined by adiabatic calorimetry in the temperature range 55–300 K. The results were used to obtain temperature dependences of the Debye characteristic temperature, entropy, and enthalpy for the solid solutions.

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关键词

Heat Capacity, Molar Heat Capacity, Solid Solu Tions, Adiabatic Calorimetry, Earth Fluoride

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