The Role of Metal Hydroxide Complexes in Late Transition Metal‐Mediated Transmetalation Reaction: The Case of Gold

Stephanie Dupuy,Luke Crawford,Michael Buhl,Alexandra M Z Slawin,Steven P Nolan

ADVANCED SYNTHESIS & CATALYSIS（2012）

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摘要

In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transmetalation group facilitator when reacted with boronic acids leading to the exceedingly rapid formation of gold-aryl bonds.

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关键词

arylboronic acids,gold hydroxide complexes,gold-aryl complexes,N-heterocyclic carbenes,transmetalation

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