Copper(Ii)-Mediated Cascade Oxidative C-C Coupling and Aromatization: Synthesis of 3-Hydroxyphenanthridinone Derivatives
Synthesis(2012)
摘要
A novel copper(II) acetate mediated synthesis of 3-hydroxyphenanthridin-6(5H)-ones from N-(3-oxocyclohex-1-enyl)benzamides was developed. The process is postulated to involve an intramolecular oxidative C(sp(2))-C(sp(3)) bond formation followed by dehydrogenative aromatization.
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关键词
copper(II) acetate,phenanthridinone,C-H functionalization,C-C oxidative coupling,dehydrogenative aromatization
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