Acid site density effects in zeolite-catalyzed 1-butene skeletal isomerization

Journal of Catalysis(2016)

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摘要
•Acid site density effects in 1-butene skeletal isomerization over H-HPM-1 are examined.•Changes (⩽0.5 per unit cell) in framework Al atoms lead to notable changes in both conversion and selectivity.•H-HPM-1 with a framework Si/Al ratio of 350 is best among the catalysts tested to date.
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关键词
Zeolite H-HPM-1,1-Butene skeletal isomerization,Brønsted acid site density,Catalyst durability
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