Heat capacities and thermodynamics of formation of flat -Al 13 nitrate – [Al 13 (OH) 24 (H 2 O) 24 ](NO 3 ) 15 ·11H 2 O

The Journal of Chemical Thermodynamics(2015)

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摘要
•ΔH of an aluminum hydroxide cluster, flat-Al13, was measured with calorimetry.•Its heat capacity at T=(2 to 300)K was measured.•Standard enthalpies, entropies, and free energies of formation are determined.•A second order phase transition was observed near T=214K.
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关键词
Heat capacity,Flat Al13,Keggin ion,Polyoxocation,Enthalpy of formation
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