Regio-selective synthesis of 1,2-aminoalcohols from epoxides and chlorohydrins

Andiappan Murugan,Vasantha Krishna Kadambar,Sreekanth Bachu, M Rajashekher Reddy,Venkatarao Torlikonda,Sulur G Manjunatha,Sridharan Ramasubramanian,Sudhir Nambiar,Gareth P Howell, Jane Withnall

Tetrahedron Letters（2012）

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摘要

A simple and efficient procedure for the regio-selective synthesis of 1,2-aminoalcohols from terminal epoxides and chlorohydrins by using NaHMDS as the source of amine is reported. The wider scope and utility of this method is demonstrated.

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关键词

1,2-Aminoalcohol,Epoxide,Chlorohydrin,NaHMDS,Epoxide opening,Regio-selective

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