Synthesis of Unprotected Carboxy Indazoles via Pd-Catalyzed Carbonylation

Philip Wainwright, Remedios Perni, Clare Vickers,Steven B Coffey,Leanne Buzon,Kenneth J Dirico,Kendra L Nelson,Zhengrong Zhao,Chris Limberakis,Kevin D Freemancook,Jeffrey W Corbett

SYNTHETIC COMMUNICATIONS（2012）

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摘要

The first published synthesis of unprotected carboxy indazoles from the corresponding bromoindazoles is described. This is achieved via Pd(II)-catalyzed carbonylation and is demonstrated to work on a variety of indazoles.

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关键词

Carbonylation,carboxylic acids,halides,indazoles,palladium

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