Synthesis of a New C-15 Phosphorus Ylide Used for the Preparation of Some -End-Group Retinoid Derivatives

Alain Valla, Nathalie Meheux,Dominique Cartier,Benoist Valla,Laurent Dufosse,Roger Labia

Synthetic Communications（2011）

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摘要

A synthesis of a new C-15 phosphorus ylide from a C-14 enaminone is reported. This reagent, which undergoes selective 1,2- or 1,4-additions with saturated and unsaturated aldehydes, may find some synthetic use for the preparation of -end-group retinoid derivatives.

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Enaminones,phosphorus ylide,retinoids

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