Leaching kinetics of neodymium in sulfuric acid from E-scrap of NdFeB permanent magnet
Korean Journal of Chemical Engineering(2014)
摘要
The leaching kinetics of neodymium in NdFeB permanent magnet powder was analyzed for the purpose of recovery of neodymium in sulfuric acid (H 2 SO 4 ) from E-scrap (electric scrap) of NdFeB permanent magnet powder treated by oxidation roasting to form a reactant. The reaction was conducted with H 2 SO 4 concentrations ranging from 2.5 to 3.5M, a pulp density of 110.8 g/L, an agitation speed of 750 rpm, and a temperature range of 30 to 70 °C. After 4 h of leaching, the neodymium content in the E-scrap powders was completely converted into a neodymium sulfate (Nd 2 (SO 4 ) 3 ) solution phase in H 2 SO 4 in the condition of 70 °C and 3.0M H 2 SO 4 . Based on a shrinking core model with sphere shape, the leaching mechanism of neodymium was determined by the rate-determining step of the ash layer diffusion. Generally, the solubility of pure rare earth elements in H 2 SO 4 is decreased with an increase in leaching temperatures. However, the leaching rate of the neodymium in E-scrap powders increased with the leaching temperatures in this study because the ash layer included in the E-scrap powder provided resistance against the leaching. Using the Arrhenius expression, the apparent activation energy values were determined to be 2.26 kJmol −1 in 2.5M H 2 SO 4 and 2.77 kJmol −1 in 3.0 M H 2 SO 4 .
更多查看译文
关键词
NdFeB Permanent Magnet, Leaching, E-scrap, Neodymium Sulfate, Ash Layer Diffusion
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要