PhI(OAc)2-mediated dearomative C–N coupling: facile construction of the spiro[indoline-3,2′-pyrrolidine] skeleton

Yali Zhou,Dengke Li,Shi Tang,Hongwei Sun,Jinbo Huang,Qiang Zhu

Organic & Biomolecular Chemistry（2018）

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摘要

A facile construction of the spiro[indole-3,2-pyrrolidine] skeleton, through diacetoxyiodobenzene (PIDA) mediated C-N bond-forming dearomatization of C3 sulfonamide linked indole derivatives, has been developed. A variety of spiro-indolepyrrolidines were obtained in moderate to excellent yields under mild conditions.

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