Modeling and model performance evaluation of sewage sludge gasification in fluidized-bed gasifiers using Aspen Plus.

A model was developed to simulate the sewage sludge gasification in an atmospheric fluidised bed gasifier using Aspen Plus. The model here presented was based on the Gibbs free energy minimisation and the restricted equilibrium method was used to calibrate it against previously published experimental data obtained in a lab-scale gasification plant. A sensitivity analysis of the model was carried out by modifying parameters such as the temperature, equivalence ratio (ER) and the steam-to-biomass ratio. The modeled results were in good agreement with the experimental data (especially when air was used as gasifying agent) and reproduced satisfactorily the experimental trends found for the gas composition, the carbon conversion (Xc) and the cold gas efficiency (CGE) under different gasification conditions. Operating at higher temperatures increased the production of H-2 and CO, as well as the Xc and the CGE. The increase in ER produced higher Xc, yet the CGE experienced slight changes due to a decrease in the lower heating value of the resulting syngas, as well as the oxidation of combustible gases. The use of air+steam as gasifying agent increased the H-2 content of the produced gases but decreased the accuracy of the model. Implications: Gasification is an available alternative to produce energy as well as several raw materials from sewage sludge. The syngas obtained from this technology totally depends on the type of gasifier and the operation conditions, which can be optimized with the help of models. In this work, a relatively simple model was built using ASPEN PLUS. Despite its simplicity, the outputs of the model are in good agreement with experimental results what makes its use interesting for assessing scaling-up possibilities from lab-scale to pilot-scale gasification processes.