Crystal structure of bis-(1,3-di-amino-propane-κ(2) N,N')bis-[2-(4-nitro-phen-yl)acetato-κO]cadmium.
Acta crystallographica. Section E, Crystallographic communications(2016)
摘要
In the structure of the title compound, [Cd(C8H6NO4)2(C3H10N2)2], the CdII atom is located on a center of symmetry with one independent Cd—O distance of 2.3547 (17) A and two Cd—N distances of 2.3265 (18) and 2.3449 (19) A. The CdII atom has an overall octahedral coordination environment. Several types of hydrogen-bonding interactions are evident. Both intra- and intermolecular interactions occur between the amino groups and the O atoms of the acetate group. These N—H⋯O hydrogen bonds lead to a layered structure extending parallel to the bc plane. In addition, weak intermolecular C—H⋯O interactions involving the nitro groups exist, leading to the formation of a three-dimensional network structure.
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关键词
1,3-diaminopropane,cadmium complex,crystal structure,nitrophenylacetic acid
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