Sydnone-Based Approach To Heterohelicenes Through 1,3-Dipolar-Cycloadditions
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY(2019)
摘要
The first approach to pyrazole-containing helicenes via sydnone-aryne [3 + 2]-cycloaddition is described. An unprecedented regioselectivity in the cycloaddition step toward the more sterically constrained product was observed in the presence of extended aromatic scaffolds. DFT calculations enabled under-standing the origin of this unexpected selectivity.
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