Chemoselective syntheses of spirodihydrofuryl and spirocyclopropyl barbiturates via cascade reactions of barbiturate-based olefins and acetylacetone

Xuebin Yan,Pei Shao,Xixi Song, Chaofei Zhang, Chang Lu, Songtao Liu, Yanli Li

Organic & Biomolecular Chemistry（2019）

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摘要

Spirodihydrofuryl and spirocyclopropyl barbiturates were chemoselectively synthesized from barbiturate-based olefins and acetylacetone in the presence of different bases and NBS.

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关键词

chemoselective syntheses,cascade reactions,olefins,barbiturate-based

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