Preparation And Performance Of Poly (Vinyl Chloride)/Aminated Poly (Vinyl Chloride) Blend Ultrafiltration Membranes

V. Murugan,D. Mohan, M.M. Rajput

DESALINATION AND WATER TREATMENT(2016)

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摘要
Polyvinyl chloride (PVC) was treated with aqueous solution of ethylenediamine to obtain aminated polyvinyl chloride (APVC). PVC/APVC blends ultrafiltration membranes, by phase inversion technique. Different polymer blend compositions with and without an additive, like Poly (ethylene glycol) of molecular weight 600Da were also prepared. The blend membranes were characterized and evaluated by scanning electron microscopy (SEM), Fourier Transform Infrared spectroscopy (FTIR), water contact angle, water content, pure water flux, and membrane porosity to investigate the influence of APVC on the final properties of the membranes. The presence of amine functional group was confirmed by FTIR spectrum. SEM analysis showed that the blend PVC membranes have thinner top layer and higher porosity in the sublayer. The blend membranes showed an increase in overall porosity, hydrophilicity, and water content, with increase in APVC content and in the presence of additive. The fouling resistant capability of the membranes was studied by Bovine serum albumin as the model foulant and flux recovery ratio (FRR) of the membranes was calculated. The blend membrane showed an increase in FRR indicating more fouling resistance than the pure PVC membrane
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关键词
Ultrafiltration, Aminated poly (vinyl chloride), Blend membranes, Hydrophilicity, Antifouling, SEM
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