谷歌浏览器插件
订阅小程序
在清言上使用

Synthesis of Enantioenriched a,a-Disubstituted Cyclopentenes Catalyzed by N-Heterocyclic Carbenes

Synthesis(2009)

引用 23|浏览4
暂无评分
摘要
rhe desymmetrization of 1,3-diketones using N-heterocyclic carbenes results in the formation of highly enantioenriched cyclopentenes in good yield. The reaction proceeds through a catalytic intramolecular aldol reaction and subsequent β-lactone formation. The expulsion of carbon dioxide at mild reaction temperatures affords the cyclopentene products.
更多
查看译文
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要