One-pot triflic anhydride-mediated synthesis of 1,2-disubstituted 2-imidazolines from N-(2-haloethyl)amides and amines

Alyssa A. Ellsworth,Christina L. Magyar, Grace E. Hubbell,Chelsea C. Theisen,Daniel Holmes,R. Adam Mosey

Tetrahedron（2016）

引用 11|浏览6

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摘要

A one-pot synthesis of 1,2-disubstituted 2-imidazolines from N-(2-haloethyl)amides has been developed. The reaction affords high yields of diverse 1,2-disubstituted 2-imidazolines from triflic anhydride-mediated dehydration of amides followed by installation of a primary amine.

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关键词

2-Imidazoline,Amidine,exo-Cyclization,Triflic anhydride

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