Facile Pd-Catalyzed Chemoselective Transfer Hydrogenation of Olefins Using Formic Acid in Water

Tianxiang Liu,Yongming Zeng,Hongxi Zhang,Ting Wei,Xia Wu,Nan Li

Tetrahedron letters（2016）

引用 27|浏览6

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摘要

An effective Pd-catalyzed reduction of olefins in water using formic acid is disclosed. A wide range of saturated hydrocarbons are obtained with an excellent conversion and remarkable chemoselectivity under mild reaction conditions. This protocol is more advantageous and less cumbersome owing to the use of HCOOH as a hydrogen source, water as a solvent, and simple workup procedure. (C) 2016 Elsevier Ltd. All rights reserved.

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关键词

Transfer hydrogenation,Palladium,Chemoselective,Environmentally friendly catalyst,Water

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