Enhanced proton conductivity at low humidity of proton exchange membranes with triazole moieties in the side chains
Journal of Membrane Science(2017)
摘要
Highly conductive, novel sulfonated poly(arylene ether) membranes with different amounts of triazole-introduced monomers (SPAE-TM) were prepared via conventional aromatic condensation reactions. The triazole-introduced monomer (TM) was used as a proton transfer moiety to increase the proton conductivities of polymer electrolyte membranes (PEMs). To compare the chemical, mechanical and thermal stabilities of non-crosslinked polymer electrolyte membranes (SPAE-TM10, SPAE-TM20), crosslinked polymer electrolyte membranes were prepared via the thermal crosslinking method (cSPAE-TM10, cSPAE-TM20). The SPAE-TM membranes exhibited excellent thermal stabilities, and the non-crosslinked SPAE-TM membranes showed satisfactory glass transition temperatures (Tg=250°C). The water uptakes and swelling ratios of the SPAE-TM membranes were successfully suppressed in comparison with the SPAE-TM0 membrane. The proton conductivities of all membranes were higher than those of Nafion 212 over a wide range of temperatures (0.211–0.256S/cm at 80°C, 100% R.H.). The SPAE-TM20 presented a proton conductivity that was 2.3 times higher than that of SPAE-TM0 at 80°C and 30% R.H.
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关键词
Polymer electrolyte membrane,Triazole,Acid-base interaction,Crosslinked membrane
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