Synthesis and characterisation of POC sp3 OP supported Ni(II) hydroxo, hydroxycarbonyl and carbonate complexes

Klara J. Jonasson,Abdelrazek H. Mousa,Ola F. Wendt

Polyhedron（2018）

引用 19|浏览6

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摘要

A nickel(II) hydroxo complex with a cyclohexyl based POCsp3OP pincer ligand reacts with CO to form the corresponding hydroxycarbonyl complex and with CO2 to form a bicarbonate species. Both compounds form hydrogen bonded dimers in the solid state.

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关键词

Nickel,Pincer,Hydroxide,Carbon monoxide,Carbon dioxide

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