Correlation of reactivity ratios, transition-metal salts and ester hydrolysis to radical polymerization of electron-deficient comonomers with 2-(N,N-dimethylamino)ethyl methacrylate as the inimer

Xiuting Wang, Lei Zhao, Qingquan Liu,Jin Song,Wenyan Huang,Guangqun Zhai

European Polymer Journal（2018）

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摘要

•Acrylamides depress hydrolysis and ensure the preferential conversion of DMAEMA.•FeCl3-DMAEMA-DMAAm pairs underwent redox-initiated reverse self-condensing ATRP.•High-MW PDMAAm (Mη > 2.0 × 107 g mol−1) was obtained via one-pot procedure.

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关键词

2-(N,N-dimethylamino)ethyl methacrylate (DMAEMA),Reverse atom transfer radical polymerization,Inimer,Reactivity ratio,N,N-dimethylacrylamide

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