Stereoselective electrochemical thioalkylation of glycine in Ni(II) coordination environment

Oleg A. Levitskiy,Yuri K. Grishin,Ksenia A. Paseshnichenko,Konstantin A. Kochetkov,Tatiana V. Magdesieva

Tetrahedron Letters（2018）

引用 14|浏览35

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摘要

•Alkylthiocyanate is a convenient reagent for thioalkylation of glycine moiety.•Nucleophilic equivalent of glycine is electrodeprotonated Schiff-base Ni complex.•Stereoselective (S)-thioalkylation of glycine moiety occurs in 70% yield and 80% de.

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关键词

Electrosynthesis,Ni(II) complexes,Stereoselectivity,Thioalkylation,Glycine

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