Volatility and thermodynamic stability of vanillin

Ana R.R.P. Almeida,Vera L.S. Freitas,Joana Campos,Maria D.M.C. Ribeiro da Silva,Manuel J.S. Monte

The Journal of Chemical Thermodynamics（2019）

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摘要

•Vapour pressures of vanillin were measured at different temperatures.•ΔfHmocr was derived from combustion calorimetry measurements.•ΔfHmog was determined from ΔfHomcr and ΔcrgHmo.•ΔfHmog was also estimated using the G3(MP2)//B3LYP method.•Thermodynamic stability of vanillin was evaluated from ΔfGmo.

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关键词

Vanillin,Sublimation,Vaporization,Fusion,Formation,Theoretical calculations

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